Select the best answer in the following
Use the following to answer question 1:
The solubility of silver phosphate (Agl04) at 25°C is 1.6 ~ 10-5 mol/L.
A) 7.6 x 10-5 M B) 6.4 x 10-5 M C) 1.6 x 10-5 M D) 3.2 x 10-5 M E) 4.8 x 10-5 M
2. Which statement below is not upheld by the second law of thermodynamics?
A) A machine is never 100%efficient.
B) Machines always waste some energy.
C) The change of entropy of the universe is always positive.
D) The entropy of a perfect crystal at 0 K is zero.
E) All of these
3. The pH in a solution H2A of 1.0 M (Ka1= 1.0 x 10-6; Ka2 = 1.0 x 10-1°) is:
A) 6.00 (B) 3.00 (C) 7.00 D) 8.00 E) none of these
4. Assume that the enthalpy of fusion of ice is 6020 J/mol and does not vary appreciably over the temperature range 270-290 K. If one mole of ice at O°C is melted by heat supplied from surroundings at 280 K, what is the entropy change in the surroundings, in JIK?
A) +22.0 B) -21.5 C) -22.0 D) 0.0 ) +21.5
Use the following to answer questions 5-7:
Determine whether the following oxides produce an acidic, basic, or neutral solution when dissolved in water:
5. MgO
6. Na2O
7. P4O10
Use the following to answer question 8:
2Fe(s) + (3/2) O2 (g) + 3H20(l) ~ 2Fe (OH)3(s) DeltaH = kJ/mol
Substance SO (J/mol K)
Fe (OH)3(s) 107
Fe(s) 27
O2 (g) 205
H20 (l) 70
9. One milliliter (1.00 mL) of acid taken from a lead storage battery is pipetted into a flask. Water and phenolphthalein indicator are added, and the solution is titrated with 0.50 M NaOH until a pink color appears;12.0 mL are required.
The number of grams ofH2SO 4 (formula weight = 98) present in one liter of the battery acid is (to within 5%)
A) 750 B) 240 C) 290 D) 480 E) 580
10. Calculate the pH at the equivalence point for the titration of 1.0 M ethylamine, C2H5NH2 by 1.0 M per chloric acid, HCIO4' (pKb for C2H5NH2 = 3.25)
A) 5.38 B) 5.53 C) 2.09 D) 2.24 E) 6.05
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